Crystallographic point group

In crystallography, a crystallographic point group is a three dimensional point group whose symmetry operations are compatible with a three dimensional crystallographic lattice. According to the crystallographic restriction it may only contain one-, two-, three-, four- and sixfold rotations or rotoinversions. This reduces the number of crystallographic point groups to 32 (from an infinity of general point groups). These 32 groups are one-and-the-same as the 32 types of morphological (external) crystalline symmetries derived in 1830 by Johann Friedrich Christian Hessel from a consideration of observed crystal forms. In 1867 Axel Gadolin, who was unaware of the previous work of Hessel, found the crystallographic point groups independently using stereographic projection to represent the symmetry elements of the 32 groups.[1]: 379 

In the classification of crystals, to each space group is associated a crystallographic point group by "forgetting" the translational components of the symmetry operations. That is, by turning screw rotations into rotations, glide reflections into reflections and moving all symmetry elements into the origin. Each crystallographic point group defines the (geometric) crystal class of the crystal.

The point group of a crystal determines, among other things, the directional variation of physical properties that arise from its structure, including optical properties such as birefringency, or electro-optical features such as the Pockels effect.

  1. ^ Authier, André (2015). "12. The Birth and Rise of the Space-Lattice Concept". Early days of X-ray crystallography. Oxford: Oxford University Press. doi:10.1093/acprof:oso/9780199659845.003.0012. ISBN 9780198754053. Retrieved 24 December 2024.

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