Decamethylcyclopentasiloxane

Decamethylcyclopentasiloxane
Skeletal formula of decamethylcyclopentasiloxane
Ball-and-stick model of the decamethylcyclopentasiloxane molecule
Ball-and-stick model of the molecule as found in the crystal structure determined by single-crystal X-ray diffraction[1]
Sample of decamethylcyclopentasiloxane
Names
Preferred IUPAC name
Decamethyl-1,3,5,7,9,2,4,6,8,10-pentaoxapentasilecane
Other names
  • Cyclopentamethicone
  • Cyclic dimethylsiloxane pentamer
  • D5
  • D5
  • 2,2,4,4,6,6,8,8,10,10-Decamethylcyclopentasiloxane
Identifiers
3D model (JSmol)
1800166
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.007.969 Edit this at Wikidata
EC Number
  • 208-764-9
MeSH Decamethylcyclopentasiloxane
RTECS number
  • GY5945200
UNII
  • InChI=1S/C10H30O5Si5/c1-16(2)11-17(3,4)13-19(7,8)15-20(9,10)14-18(5,6)12-16/h1-10H3 checkY
    Key: XMSXQFUHVRWGNA-UHFFFAOYSA-N checkY
  • InChI=1/C10H30O5Si5/c1-16(2)11-17(3,4)13-19(7,8)15-20(9,10)14-18(5,6)12-16/h1-10H3
    Key: XMSXQFUHVRWGNA-UHFFFAOYAC
  • C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1
  • O1[Si](O[Si](O[Si](O[Si](O[Si]1(C)C)(C)C)(C)C)(C)C)(C)C
Properties
[(CH3)2SiO]5
Molar mass 370.770 g·mol−1
Appearance Colourless liquid
Density 0.958 g/cm3
Melting point −47 °C; −53 °F; 226 K
Boiling point 210 °C (410 °F; 483 K)
17.03±0.72 ppb (23 °C) [2]
log P 8.07[3]
Vapor pressure 20.4±1.1 Pa (25 °C) [4]
Viscosity 3.74 cP
Hazards
GHS labelling:
GHS02: FlammableGHS08: Health hazard
Warning
H226, H361, H412, H413
P201, P202, P210, P233, P240, P241, P242, P243, P273, P280, P281, P303+P361+P353, P308+P313, P370+P378, P403+P235, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g. diesel fuelInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
2
0
Flash point 73 °C (163 °F; 346 K)
Safety data sheet (SDS) External MSDS
Related compounds
Octamethylcyclotetrasiloxane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Decamethylcyclopentasiloxane, also known as D5 and D5, is an organosilicon compound with the formula [(CH3)2SiO]5. It is a colorless and odorless liquid that is slightly volatile.[5]

  1. ^ S. Parsons, D. Rankin, P. A. Wood (2004). "CSD Communication YAGTOQ: decamethylpentasilsesquioxane". Cambridge Structural Database: Access Structures. Cambridge Crystallographic Data Centre. doi:10.5517/cc89wzd. Retrieved 2021-08-18.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  2. ^ Sudarsanan Varaprath; Cecil L. Frye; Jerry Hamelink (1996). "Aqueous solubility of permethylsiloxanes (silicones)". Environmental Toxicology and Chemistry. 15 (8): 1263–1265. Bibcode:1996EnvTC..15.1263V. doi:10.1002/etc.5620150803.
  3. ^ Shihe Xu, Bruce Kropscott (2012). "Method for Simultaneous Determination of Partition Coefficients for Cyclic Volatile Methylsiloxanes and Dimethylsilanediol". Analytical Chemistry. 84 (4): 1948–1955. doi:10.1021/ac202953t. PMID 22304371.
  4. ^ Ying Duan Lei; Frank Wania; Dan Mathers (2010). "Temperature-Dependent Vapor Pressure of Selected Cyclic and Linear Polydimethylsiloxane Oligomers". Journal of Chemical & Engineering Data. 55 (12): 5868–5873. doi:10.1021/je100835n.
  5. ^ Record of Decamethylcyclopentasiloxan in the GESTIS Substance Database of the Institute for Occupational Safety and Health, accessed on 25. September 2015.

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