Back دئوتراتد کولوروفرم AZB Cloroform deuterat Catalan Deuterokloroformo Basque دئوتراتد کلروفرم Persian Chloroforme deutéré French 重水素化クロロホルム Japanese Gedeutereerd chloroform Dutch Deuterisani hloroform Serbo-Croatian Deuterovaný chloroform Slovak Deuterisani hloroform Serbian

Deuterated chloroform

Deuterated chloroform
Stereo, skeletal formula of deuterated chloroform
Stereo, skeletal formula of deuterated chloroform
Spacefill model of deuterated chloroform
Spacefill model of deuterated chloroform
Names
IUPAC name
trichloro(deuterio)methane[1]
Other names
Chloroform-d
Deuterochloroform
Identifiers
3D model (JSmol)
1697633
ChEBI
ChemSpider
ECHA InfoCard 100.011.585 Edit this at Wikidata
EC Number
  • 212-742-4
UNII
UN number 1888
  • InChI=1S/CHCl3/c2-1(3)4/h1H/i1D checkY
    Key: HEDRZPFGACZZDS-MICDWDOJSA-N checkY
  • InChI=1/CHCl3/c2-1(3)4/h1H/i1D
    Key: HEDRZPFGACZZDS-MICDWDOJEH
  • [2H]C(Cl)(Cl)Cl
Properties
CDCl3
Molar mass 120.384 g/mol
Appearance Colorless liquid
Odor chloroform-like
Density 1.500 g/cm3
Melting point −64 °C (−83 °F; 209 K)
Boiling point 61 °C (142 °F; 334 K)
Hazards
GHS labelling:
GHS05: CorrosiveGHS07: Exclamation markGHS08: Health hazard
Danger
H302, H315, H319, H331, H336, H351, H361, H372, H373
P201, P202, P260, P261, P264, P270, P271, P280, P281, P301+P312, P302+P352, P304+P340, P305+P351+P338, P308+P313, P311, P312, P314, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Related compounds
Related compounds
 Chloroform

Deuterated dichloromethane

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Deuterated chloroform, also known as chloroform-d, is the organic compound with the formula CDCl3. Deuterated chloroform is a common solvent used in NMR spectroscopy.[2] The properties of CDCl3 and ordinary CHCl3 (chloroform) are virtually identical.

Deuterochloroform was first made in 1935 during the years of research on deuterium.[3]

  1. ^ "Chloroform-d".
  2. ^ Fulmer, Gregory R.; Miller, Alexander J. M.; Sherden, Nathaniel H.; Gottlieb, Hugo E.; Nudelman, Abraham; Stoltz, Brian M.; Bercaw, John E.; Goldberg, Karen I. (2010). "NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist" (PDF). Organometallics. 29 (9): 2176–2179. doi:10.1021/om100106e.
  3. ^ Chloroform-d (Deuteriochloroform), F. W. Breuer , J. Am. Chem. Soc. 1935, 57, 11, 2236–2237 (November 1, 1935) [1]
From Wikipedia, the free encyclopedia · View on Wikipedia

Developed by Nelliwinne