The search for the presence of lunar water has attracted considerable attention and motivated several recent lunar missions, largely because of water's usefulness in making long-term lunar habitation feasible.[1]
The Moon is believed to be generally anhydrous after analysis of Apollo mission soil samples. It is understood that any water vapor on the surface would generally be decomposed by sunlight, leaving hydrogen and oxygen lost to outer space. However, subsequent robotic probes found evidence of water, especially of water ice in some permanently-shadowed craters on the Moon; and in 2018 water ice was confirmed in multiple locations.[2][3][4][5] This water ice is not in the form of sheets of ice on the surface nor just under the surface, but there may be small (less than about 10 centimetres (3.9 in)) chunks of ice mixed into the regolith, and some water is chemically bonded with minerals.[6][7][8] Other experiments have detected water molecules in the negligible lunar atmosphere,[9] and even some in low concentrations at the Moon's sunlit surface.[10]
On the Moon, water (H2O) and hydroxyl group (-OH) are not present as free water but are chemically bonded within minerals as hydrates and hydroxides, existing in low concentrations across the lunar surface.[11][12]Adsorbed water is estimated to be traceable at levels of 10 to 1000 ppm.[13] The presence of water may be attributed to two primary sources: delivery over geological timescales via impacts and in situ production through interactions of solar wind hydrogen ions with oxygen-bearing minerals.[14][15] Confirmed hydroxyl-bearing materials include glasses, apatite [Ca5(PO4)3(F, Cl, OH)], and novograblenovite [(NH4)MgCl3·6H2O].
NASA's Ice-Mining Experiment-1 (set to launch on the PRIME-1 mission no earlier than late 2024) is intended to answer whether or not water ice is present in usable quantities in the southern polar region.[16]
^Elston, D.P. (1968) "Character and Geologic Habitat of Potential Deposits of Water, Carbon and Rare Gases on the Moon", Geological Problems in Lunar and Planetary Research, Proceedings of AAS/IAP Symposium, AAS Science and Technology Series, Supplement to Advances in the Astronautical Sciences., p. 441