Methanesulfonyl chloride

Methanesulfonyl chloride
Names
Preferred IUPAC name
Methanesulfonyl chloride
Other names
Mesyl chloride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.004.279 Edit this at Wikidata
UNII
  • CS(Cl)(=O)=O
Properties
CH3SO2Cl
Molar mass 114.54 g·mol−1
Appearance colorless liquid
Odor Pungent, unpleasant[1]
Density 1.480 g/cm3
Melting point −32 °C (−26 °F; 241 K)[2]
Boiling point 161 °C (322 °F; 434 K) (at 730 mmHg)
Reacts[3][4]
Solubility Soluble in alcohol, ether and most organic solvents[5]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Lachrymator, highly toxic, corrosive
Flash point >110 °C (230 °F; 383 K)[6]
Related compounds
Other anions
Methanesulfonyl fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Methanesulfonyl chloride (mesyl chloride) is an organosulfur compound with the formula CH3SO2Cl. Using the organic pseudoelement symbol Ms for the methanesulfonyl (or mesyl) group CH3SO2–, it is frequently abbreviated MsCl in reaction schemes or equations. It is a colourless liquid that dissolves in polar organic solvents but is reactive toward water, alcohols, and many amines. The simplest organic sulfonyl chloride, it is used to make methanesulfonates and to generate the elusive molecule sulfene (methylenedioxosulfur(VI)).[7]

  1. ^ "Methanesulfonyl chloride".
  2. ^ "Methanesulfonyl chloride".
  3. ^ cameochemicals.noaa.gov/chemical/11835
  4. ^ "MSDS". Archived from the original on 2005-04-30. Retrieved 2013-01-14.
  5. ^ "Methanesulfonyl chloride".
  6. ^ "Methanesulfonyl chloride".
  7. ^ Valerie Vaillancourt, Michele M. Cudahy, Matthew M. Kreilein and Danielle L. Jacobs "Methanesulfonyl Chloride" in E-EROS Encyclopedia for Reagents in Organic Synthesis doi:10.1002/047084289X.rm070.pub2

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