Pentafluorosulfur hypofluorite

Pentafluorosulfur hypofluorite
Names
IUPAC name
Pentafluorosulfur hypofluorite
Other names
  • Sulfur fluoride hypofluorite
  • Thionyl fluoride hypofluorite
Identifiers
3D model (JSmol)
  • InChI=1S/F6OS/c1-7-8(2,3,4,5)6
    Key: DGQBNDRZRZYTER-UHFFFAOYSA-N
  • S(F)(F)(F)(F)(F)OF
Properties
SOF6
Appearance Colorless gas
Density 1.947 at -47.2 °C[1]
Melting point −86 °C (−123 °F; 187 K)[1]
Boiling point −35.1 °C (−31.2 °F; 238.1 K)[1]
Reacts with water
log P 6.03633-420.35/T-78360/T²[1]
Related compounds
Related oxohalides
Thionyl tetrafluoride
Thionyl fluoride,
sulfonyl fluoride
Related compounds
sulfuryl fluoride
sulfur hexafluoride
pentafluorooxosulfuric acid
bis-(pentafluorosulfur) oxide
bis-(pentafluorosulfur) peroxide
bis-(pentafluorosulfur) trioxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Pentafluorosulfur hypofluorite is an oxyfluoride of sulfur in the +6 oxidation state, with a fluorine atom attached to oxygen. The formula is SOF6. In standard conditions it is a gas.[1]

  1. ^ a b c d e Dudley, F. B.; Cady, G. H.; Eggers, D. F. (April 1956). "Pentafluorosulfur Hypofluorite and Thionyl Tetrafluoride". Journal of the American Chemical Society. 78 (8): 1553–1557. Bibcode:1956JAChS..78.1553D. doi:10.1021/ja01589a013.

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