Chemical element with atomic number 31 (Ga)
Gallium, 31 Ga Pronunciation (GAL -ee-əm ) Appearance silvery blue
Atomic number (Z ) 31 Group group 13 (boron group) Period period 4 Block p-block Electron configuration [Ar ] 3d10 4s2 4p1 Electrons per shell 2, 8, 18, 3 Phase at STP solid Melting point 302.9146 K (29.7646 °C, 85.5763 °F) Boiling point 2676 K (2403 °C, 4357 °F)[ 3] [ 4] Density (at 20° C) 5.907 g/cm3 [ 5] when liquid (at m.p. ) 6.095 g/cm3 Heat of fusion 5.59 kJ/mol Heat of vaporization 256 kJ/mol[ 3] Molar heat capacity 25.86 J/(mol·K) Vapor pressure
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
1310
1448
1620
1838
2125
2518
Oxidation states common: +3
−5,[ 6] −4,[ 6] −3,[ 7] −2,[ 6] −1,[ 8] 0,[ 9] +1,[ 10] +2[ 10] Electronegativity Pauling scale: 1.81 Ionization energies 1st: 578.8 kJ/mol 2nd: 1979.3 kJ/mol 3rd: 2963 kJ/mol (more ) Atomic radius empirical: 135 pm Covalent radius 122±3 pm Van der Waals radius 187 pm Spectral lines of galliumNatural occurrence primordial Crystal structure base-centered orthorhombic (oS8 ) Lattice constants a = 452.05 pmb = 766.25 pmc = 452.66 pm (at 20 °C)[ 5] Thermal expansion 20.5× 10−6 /K (at 20 °C)[ 5] [ a] Thermal conductivity 40.6 W/(m⋅K) Electrical resistivity 270 nΩ⋅m (at 20 °C) Magnetic ordering diamagnetic Molar magnetic susceptibility −21.6× 10−6 cm3 /mol (at 290 K)[ 11] Young's modulus 9.8 GPa Speed of sound thin rod 2740 m/s (at 20 °C) Poisson ratio 0.47 Mohs hardness 1.5 Brinell hardness 56.8–68.7 MPa CAS Number 7440-55-3 Naming after Gallia (Latin for: France), homeland of the discoverer Prediction Dmitri Mendeleev (1871) Discovery and first isolationLecoq de Boisbaudran (1875)
Category: Gallium | references
child table, as reused in {IB-Ga}
^ "Standard Atomic Weights: Gallium" . CIAAW . 1987.
^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)" . Pure and Applied Chemistry . doi :10.1515/pac-2019-0603 . ISSN 1365-3075 .
^ a b Zhang Y; Evans JRG; Zhang S (2011). "Corrected Values for Boiling Points and Enthalpies of Vaporization of Elements in Handbooks" . J. Chem. Eng. Data . 56 (2): 328– 337. doi :10.1021/je1011086 .
^ "Gallium (CAS Number 7440-55-3) : Strem Product Catalog" . Strem Chemicals Inc . Retrieved 4 December 2023 .
^ a b c d Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements . Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9 .
^ a b c Hofmann, Patrick (1997). Colture. Ein Programm zur interaktiven Visualisierung von Festkörperstrukturen sowie Synthese, Struktur und Eigenschaften von binären und ternären Alkali- und Erdalkalimetallgalliden (PDF) (Thesis) (in German). PhD Thesis, ETH Zurich. p. 72. doi :10.3929/ethz-a-001859893 . hdl :20.500.11850/143357 . ISBN 978-3728125972 .
^ Ga(−3) has been observed in LaGa, see Dürr, Ines; Bauer, Britta; Röhr, Caroline (2011). "Lanthan-Triel/Tetrel-ide La(Al,Ga)x (Si,Ge)1-x . Experimentelle und theoretische Studien zur Stabilität intermetallischer 1:1-Phasen" (PDF) . Z. Naturforsch. (in German). 66b : 1107– 1121.
^ Ga(−1) has been observed in LiGa; see Holleman, Arnold F.; Wiberg, Egon; Wiberg, Nils (2008). Lehrbuch der Anorganischen Chemie (in German) (102 ed.). Walter de Gruyter. p. 1185. ISBN 9783110206845 .
^ Ga(0) is known in gallium monoiodide ; see Widdifield, Cory M.; Jurca, Titel; Richeson, Darrin S.; Bryce, David L. (2012-03-16). "Using 69/71Ga solid-state NMR and 127I NQR as probes to elucidate the composition of "GaI" " . Polyhedron . 35 (1): 96– 100. doi :10.1016/j.poly.2012.01.003 . ISSN 0277-5387 .
^ a b Greenwood, Norman N. ; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann . p. 28. ISBN 978-0-08-037941-8 .
^ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics . Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4 .
^ a b Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF) . Chinese Physics C . 45 (3): 030001. doi :10.1088/1674-1137/abddae .
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