Tetrakis(triphenylphosphine)palladium(0)

Tetrakis(triphenylphosphine)­palladium(0)
3D model of the tetrakis(triphenylphosphine)palladium(0) molecule
3D model of the tetrakis(triphenylphosphine)palladium(0) molecule
Tetrakis(triphenylphosphine)palladium(0)
Tetrakis(triphenylphosphine)palladium(0)
Names
IUPAC name
Tetrakis(triphenylphosphane)palladium(0)
Other names
TPP palladium(0)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.609 Edit this at Wikidata
EC Number
  • 238-086-9
UNII
  • InChI=1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
    Key: NFHFRUOZVGFOOS-UHFFFAOYSA-N
  • [Pd-4]([P+](c1ccccc1)(c1ccccc1)c1ccccc1)([P+](c1ccccc1)(c1ccccc1)c1ccccc1)([P+](c1ccccc1)(c1ccccc1)c1ccccc1)[P+](c1ccccc1)(c1ccccc1)c1ccccc1
Properties
C72H60P4Pd
Molar mass 1155.59 g·mol−1
Appearance Bright yellow to chartreuse crystals
Melting point decomposes around 115 °C
Insoluble
Structure
four triphenylphosphine monodentate
ligands attached to a central Pd(0)
atom in a tetrahedral geometry
tetrahedral
0 D
Hazards
GHS labelling:[1]
GHS07: Exclamation mark
Warning
H302, H317, H413
P261, P264, P270, P272, P273, P280, P301+P312, P302+P352, P330, P333+P313, P363, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability (yellow): no hazard codeSpecial hazards (white): no code
2
1
Related compounds
Related complexes
chlorotris(triphenylphosphine)rhodium(I)
tris(dibenzylideneacetone)dipalladium(0)

Tetrakis(triphenylphosphine)platinum(0)
Tetrakis(triphenylphosphine)nickel(0)

Related compounds
triphenylphosphine
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Tetrakis(triphenylphosphine)palladium(0) (sometimes called quatrotriphenylphosphine palladium) is the chemical compound [Pd(P(C6H5)3)4], often abbreviated Pd(PPh3)4, or rarely PdP4. It is a bright yellow crystalline solid that becomes brown upon decomposition in air.

  1. ^ "Tetrakis(triphenylphosphine)palladium". pubchem.ncbi.nlm.nih.gov.

From Wikipedia, the free encyclopedia · View on Wikipedia

Developed by Nelliwinne